A novel quinoxaline bearing electroactive monomer: Pyrrole as the donor moiety

Taskin A. T., Balan A., Epik B., Yildiz E., Udum Y. A., TOPPARE L. K.

ELECTROCHIMICA ACTA, vol.54, no.23, pp.5449-5453, 2009 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Review
  • Volume: 54 Issue: 23
  • Publication Date: 2009
  • Doi Number: 10.1016/j.electacta.2009.04.042
  • Journal Name: ELECTROCHIMICA ACTA
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.5449-5453
  • Middle East Technical University Affiliated: Yes

Abstract

A novel electroactive monomer 5,8-di(1H-pyrrol-2-yl)-2,3-di(thiophen-2-yl)quinoxaline (PTQ) was successfully synthesized and its electrochromic properties were reported. Nuclear magnetic resonance ((1)H NMR-(13)C NMR) and mass spectroscopy were used to characterize the monomer. The monomer was electrochemically polymerized in the presence of tetrabutylammonium perchlorate (TBAP) as supporting electrolyte in dichloromethane. Monomer reveals relatively low oxidation potential at +0.70V. Spectroelectrochemical behaviors and switching ability of homopolymer were investigated by UV-vis spectroscopy and cyclic voltammetry. Two pi-pi* transitions were observed at 400 and 815 nm with a low band gap, 1.0 eV. Polymer possesses 66% optical contrast in the Near IR region, which may be promising in NIR electrochromic device applications. (C) 2009 Elsevier Ltd. All rights reserved.