High temperature bromination. Part 18: Bromination of benzonorbornadiene derivatives: Polybrominated benzonorbornenes and benzonorbornadienes

Dastan A., Balci M.

TETRAHEDRON, vol.61, no.23, pp.5481-5488, 2005 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 61 Issue: 23
  • Publication Date: 2005
  • Doi Number: 10.1016/j.tet.2005.03.132
  • Journal Name: TETRAHEDRON
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.5481-5488
  • Keywords: benzonorbornadiene bromination, Wagner-Meerwein rearrangement, polybromides, FLAME-RETARDANT, EXO ATTACK, BROMOBENZONORBORNENES, HALOFLUORINATION, PHOTOOXYGENATION, NORBORNADIENE, SUBSTITUENTS, PRODUCTS
  • Middle East Technical University Affiliated: No

Abstract

The low and high temperature bromination reactions of bromobenzonorbornadiene derivatives were studied and the possible role of a neighboring group in rearrangements was investigated. New polybrominated benzonorbornadiene and benzonorbornene derivatives were synthesized. All compounds were characterized property Using NMR spectroscopy. (c) 2005 Elsevier Ltd. All rights reserved.