Uncatalyzed addition of TMSCN to acylphosphonates

Demir A. S., Reis O., Kayalar M., Eymur S., Reis B.

SYNLETT, no.19, pp.3329-3333, 2006 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Publication Date: 2006
  • Doi Number: 10.1055/s-2006-951558
  • Journal Name: SYNLETT
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.3329-3333
  • Middle East Technical University Affiliated: Yes


The cyanosilylations of various alkyl- and arylphosphonates under comparatively mild conditions furnished the trimethyl-silyloxycyanophosphonates in high yield. The addition to ketophosphonate functions works without the influence of a catalyst.