Uncatalyzed addition of TMSCN to acylphosphonates

Demir A. S., Reis O., Kayalar M., Eymur S., Reis B.

SYNLETT, sa.19, ss.3329-3333, 2006 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1055/s-2006-951558
  • Dergi Adı: SYNLETT
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.3329-3333
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

The cyanosilylations of various alkyl- and arylphosphonates under comparatively mild conditions furnished the trimethyl-silyloxycyanophosphonates in high yield. The addition to ketophosphonate functions works without the influence of a catalyst.