Atıf İçin Kopyala
Cokol N. K., Kaya S., BALCI M.
TETRAHEDRON LETTERS, cilt.58, sa.28, ss.2732-2735, 2017 (SCI-Expanded)
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Yayın Türü:
Makale / Tam Makale
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Cilt numarası:
58
Sayı:
28
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Basım Tarihi:
2017
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Doi Numarası:
10.1016/j.tetlet.2017.05.099
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Dergi Adı:
TETRAHEDRON LETTERS
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Derginin Tarandığı İndeksler:
Science Citation Index Expanded (SCI-EXPANDED), Scopus
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Sayfa Sayıları:
ss.2732-2735
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Anahtar Kelimeler:
Oxabicycloheptene, Aminoinositol, Diacylazide, Curtius rearrangement, Neighbouring group participation, RING-OPENING REACTIONS, DIELS-ALDER REACTIONS, STEREOSPECIFIC SYNTHESIS, STEREOSELECTIVE-SYNTHESIS, BRANCHED CARBASUGARS, ACID, AMINOCYCLITOL, CONSTRUCTION, CATALYST, ANALOGS
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Orta Doğu Teknik Üniversitesi Adresli:
Evet
Özet
The regio- and stereoselective synthesis of a new synthon, trans-3,8-dioxatricyclo[3.2.1.0(2,4)]octane-6,7-diamine, from 7-oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate is reported. Transformation of the acid functionalities to acyl azides followed by Curtius rearrangement gave the corresponding trans-diisocyanate, which was reacted with HCl to produce a trans-diamino compound that is a potentially important synthon for the versatile synthesis of aminocyclitols. (C) 2017 Elsevier Ltd. All rights reserved.