3,5-Dimethylpyrazolium Chlorochromate(VI): An Efficient Reagent for Solvent-Free Oxidation of Organic Substrates
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, cilt.42, sa.5, ss.634-637, 2012 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 42 Sayı: 5
- Basım Tarihi: 2012
- Doi Numarası: 10.1080/15533174.2011.614990
- Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.634-637
- Orta Doğu Teknik Üniversitesi Adresli: Hayır
Özet
A new chromium(VI) reagent 3,5-dimethylpyrazolium chlorochromate, C5H8N2H[CrO3Cl] (DmpzHCC), was synthesized and used for the selective oxidation of various organic compounds under solvent-free conditions with high efficiency. This new compound has certain advantages over its companion analogues in terms of controlled acidity, amount of oxidant, lack of solvent, short reaction times, and high yields.