Synthesis and characterizations of N,N,N ',N '-tetrakis (diphenylphosphino)ethylendiamine derivatives: Use of palladium(II) complex as pre-catalyst in Suzuki coupling and Heck reactions


AKBA O., DURAP F., AYDEMİR M., BAYSAL A., Guemguem B., ÖZKAR S.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, cilt.694, sa.5, ss.731-736, 2009 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 694 Sayı: 5
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1016/j.jorganchem.2008.11.063
  • Dergi Adı: JOURNAL OF ORGANOMETALLIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.731-736
  • Anahtar Kelimeler: Aminophosphine, Suzuki coupling, Heck reaction, Catalysis, Palladium, Platinum, LIGANDS (PH2P)(2)NH DPPA, MIXED-METAL CLUSTERS, COORDINATION CHEMISTRY, ARYL BROMIDES, NONCONVENTIONAL METHODOLOGIES, AMINOPHOSPHINE LIGANDS, AMINATION REACTIONS, CRYSTAL-STRUCTURE, BOND FORMATION, HYDROGENATION
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

Oxidation of N,N,N',N'-tetrakis(diphenylphosphino)ethylendiamine (1) with elemental sulfur and selenium gives the corresponding sulfide and selenide, respectively, [(Ph2P(E))(2)NCH2CH2N(P(E)Ph-2)(2)] (E: S 1a, Se 1b). Complexes of 1 [(M2Cl4){(Ph2P)(2)NCH2CH2N(PPh2)(2)}] (M: Ni(II) 1c, Pd(II) 1d, Pt(II) 1e) were prepared by the reaction of 1 with NiCl2 or [MCl2(COD)] (M = Pd, Pt). The new compounds were characterized by NMR, IR spectroscopy and elemental analysis. The catalytic activity of Pd(II) complex 1d was tested in the Suzuki coupling reaction and Heck reaction. The palladium complex 1d catalyses the Heck reaction between styrene and aryl bromides as well as Suzuki coupling reaction between phenylboronic acid and arylbromides affording stilbenes and biphenyls in high yield, respectively. (C) 2008 Elsevier B.V. All rights reserved.