Reinvestigation of the synthetic and mechanistic aspects of Mn(III) acetate mediated oxidation of enones

Demir A., Reis O., Igdir A.

TETRAHEDRON, cilt.60, sa.15, ss.3427-3432, 2004 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 60 Sayı: 15
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1016/j.tet.2004.02.039
  • Dergi Adı: TETRAHEDRON
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.3427-3432
  • Anahtar Kelimeler: enones, oxidation, Mn(OAc)(3), alkenes, MANGANESE(III) ACETATE, ALPHA-ACETOXY, CLEAVAGE, 2-CYCLOHEXENONES, CYCLIZATIONS, ENANTIOMERS, KETONES
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

Mn(OAc)(3) mediated alpha'-acetoxylation of alpha,beta-unsaturated enones is reinvestigated from a synthetic and mechanistic point of view and an improved procedure based on the use of acetic acid as a co-solvent is presented. Excellent results were obtained for a variety of structurally diverse and synthetically important enones under the optimized conditions. (C) 2004 Elsevier Ltd. All rights reserved.