Atıf İçin Kopyala
Demir A., Reis O., Igdir A.
TETRAHEDRON, cilt.60, sa.15, ss.3427-3432, 2004 (SCI-Expanded)
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Yayın Türü:
Makale / Tam Makale
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Cilt numarası:
60
Sayı:
15
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Basım Tarihi:
2004
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Doi Numarası:
10.1016/j.tet.2004.02.039
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Dergi Adı:
TETRAHEDRON
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Derginin Tarandığı İndeksler:
Science Citation Index Expanded (SCI-EXPANDED), Scopus
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Sayfa Sayıları:
ss.3427-3432
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Anahtar Kelimeler:
enones, oxidation, Mn(OAc)(3), alkenes, MANGANESE(III) ACETATE, ALPHA-ACETOXY, CLEAVAGE, 2-CYCLOHEXENONES, CYCLIZATIONS, ENANTIOMERS, KETONES
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Orta Doğu Teknik Üniversitesi Adresli:
Evet
Özet
Mn(OAc)(3) mediated alpha'-acetoxylation of alpha,beta-unsaturated enones is reinvestigated from a synthetic and mechanistic point of view and an improved procedure based on the use of acetic acid as a co-solvent is presented. Excellent results were obtained for a variety of structurally diverse and synthetically important enones under the optimized conditions. (C) 2004 Elsevier Ltd. All rights reserved.