Hydrothermal BaTiO3 thin films from nanostructured Ti templates

Akyildiz H., Casper M. D. , Ayguen S. M. , Lam P. G. , Maria J. P.

JOURNAL OF MATERIALS RESEARCH, vol.26, no.4, pp.592-599, 2011 (Peer-Reviewed Journal) identifier identifier

  • Publication Type: Article / Article
  • Volume: 26 Issue: 4
  • Publication Date: 2011
  • Doi Number: 10.1557/jmr.2010.102
  • Journal Indexes: Science Citation Index Expanded, Scopus
  • Page Numbers: pp.592-599


Polycrystalline BaTiO3 thin films have been prepared by hydrothermal reaction with sputter-deposited nanostructured reactive Ti templates designed to control net diffusion direction and distance. Templates were prepared in two morphologies, i.e., planar and nanopillar. The samples produced from flat templates showed sluggish transformation kinetics and an eventual termination of reaction without fully consuming the Ti metal. Templates with pillar morphology, on the other hand, could be transformed to phase-pure BaTiO3, independent of the template thickness. In the as-precipitated state, those films revealed a permittivity of similar to 1000 and loss tangent values around 0.1 with mild dispersion in the kilohertz frequency range. Annealing these films under forming gas containing 1 vol% H-2 balance N-2 for 3 h at 200 degrees C decreased high-field losses to 0.06 and reduced dispersion. Mn incorporation as an in situ acceptor dopant was also explored. Addition of Mn during hydrothermal treatment further improved the electrical properties. Annealing under the same postgrowth conditions virtually eliminated the frequency dispersion in the range of 1 kHz to 1 MHz, while maintaining permittivity values in the range of 350.