Effectiveness of a novel polyaniline@Fe-ZSM-5 hybrid composite for Orange G dye removal from aqueous media: Experimental study and advanced statistical physics insights

Imgharn A., Anchoum L., Hsini A., Naciri Y., Laabd M., Mobarak M., ...Daha Fazla

Chemosphere, cilt.295, 2022 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 295
  • Basım Tarihi: 2022
  • Doi Numarası: 10.1016/j.chemosphere.2022.133786
  • Dergi Adı: Chemosphere
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Aerospace Database, Aqualine, Aquatic Science & Fisheries Abstracts (ASFA), Artic & Antarctic Regions, BIOSIS, Biotechnology Research Abstracts, CAB Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, EMBASE, Environment Index, Food Science & Technology Abstracts, Geobase, Greenfile, MEDLINE, Metadex, Pollution Abstracts, Public Affairs Index, Veterinary Science Database, Civil Engineering Abstracts
  • Anahtar Kelimeler: Polyaniline, Fe-ZSM-5, Composite, Dye removal, Advanced statistical physics, Regeneration, EFFICIENT REMOVAL, ACTIVATED CARBON, ADSORPTION-ISOTHERMS, HEXAVALENT CHROMIUM, BINARY ADSORPTION, ANIONIC DYES, POLYANILINE, NANOCOMPOSITE, CHITOSAN, ACID
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

© 2022 Elsevier LtdA polyaniline@Fe-ZSM-5 composite was synthesized via an in situ interfacial polymerization procedure. The morphology, crystallinity, and structural features of the as-developed PANI@Fe-ZSM-5 composite were assessed using scanning electron microscopy – energy dispersive spectroscopy (SEM-EDS), X-ray diffraction (XRD), Fourier-transform infrared (FTIR) spectroscopy, and X-ray photoelectron spectroscopy (XPS). The composite was efficiently employed for the first time as an adsorbent Orange G (OG) dyestuff from water. The OG dye adsorption performance was investigated as a function of several operating conditions. The kinetic study demonstrated that a pseudo-second-order model was appropriate to anticipate the OG adsorption process. The maximum adsorption capacity was found to be 217 mg/g. The adsorption equilibrium data at different temperatures were calculated via advanced statistical physics formalism. The entropy function indicated that the disorder of OG molecules improved at low concentrations and lessened at high concentrations. The free enthalpy and internal energy functions suggested that the OG adsorption was a spontaneous process and physisorption in nature. Regeneration investigation showed that the PANI@Fe-ZSM-5 could be effectively reused up to five cycles. The main results of this work provided a deep insight on the experimental study supported by advanced statistical physics prediction for the adsorption of Orange G dye onto the novel polyaniline@Fe-ZSM-5 hybrid composite. Additionally, the experimental and advanced statistical physics findings stated in this study may arouse research interest in the field of wastewater treatment.