Trichloronitromethane with acyl chlorides in the presence of tin(II) chloride: Synthesis of trichloronitro ketones

DEMİR, AYHAN; TANYELİ, CİHANGİR; AKSOY, HAVA; Gulbeyaz, V.; Mahasneh, A.S.

doi:10.1055/s-1995-4055

Trichloronitromethane with acyl chlorides in the presence of tin(II) chloride: Synthesis of trichloronitro ketones

DEMİR A. G., TANYELİ C., AKSOY H., Gulbeyaz V., Mahasneh A.

Synthesis, sa.9, ss.1071-1073, 1995 (Scopus)

Yayın Türü: Makale / Tam Makale
Basım Tarihi: 1995
Doi Numarası: 10.1055/s-1995-4055
Dergi Adı: Synthesis
Derginin Tarandığı İndeksler: Scopus
Sayfa Sayıları: ss.1071-1073
Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

Trichloronitromethane adds to acid chlorides in the presence of tin(II) chloride to yield dichloronitro ketones via a substitution reaction. Reduction and dechlorination of the dichloronitro ketones give dichloroamino alcohols and nitro ketones, respectively, in good yield.