Trichloronitromethane with acyl chlorides in the presence of tin(II) chloride: Synthesis of trichloronitro ketones

DEMİR A. G., TANYELİ C., AKSOY H., Gulbeyaz V., Mahasneh A.

Synthesis, no.9, pp.1071-1073, 1995 (Scopus) identifier

  • Publication Type: Article / Article
  • Publication Date: 1995
  • Doi Number: 10.1055/s-1995-4055
  • Journal Name: Synthesis
  • Journal Indexes: Scopus
  • Page Numbers: pp.1071-1073
  • Middle East Technical University Affiliated: Yes

Abstract

Trichloronitromethane adds to acid chlorides in the presence of tin(II) chloride to yield dichloronitro ketones via a substitution reaction. Reduction and dechlorination of the dichloronitro ketones give dichloroamino alcohols and nitro ketones, respectively, in good yield.