Kesterite Films Processed with Organic Solvents: Unveiling the Impact of Carbon-Rich Fine-Grain-Layer Formation on Solar-Cell Performance


Javed A., Donmez D., Jones M. D. K., Qu Y., GÜNBAŞ E. G., YERCİ S.

Energy Technology, 2024 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Review
  • Publication Date: 2024
  • Doi Number: 10.1002/ente.202400646
  • Journal Name: Energy Technology
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Applied Science & Technology Source, CAB Abstracts, Chimica, Compendex, Environment Index, Greenfile, INSPEC
  • Keywords: carbon-rich, fine-grain, kesterites, nanocrystals, organic solvents
  • Middle East Technical University Affiliated: Yes

Abstract

Solution-processed kesterite (copper zinc tin sulfide [CZTS]) solar cells attract significant attention owing to their low cost, ease of large-scale production, and earth-abundant elemental composition, which make these devices promising to fulfill the ever-increasing demand of the photovoltaic (PV) industry. Compared to the performances of expensive vacuum-based techniques, colloidal nanocrystal kesterite solar cells garner substantial interest due to their economical and rapid processing. Led by the hot-injection method, organic solvent-based techniques are widely adopted to realize CZTS nanocrystal inks. With organic solvents, ligand-stabilized nanoparticles are formed leading to dispersive and homogenous kesterite inks. However, the presence of carbon-rich ligands around the nanocrystal surface often leads to the formation of a fine-grain layer that is rich in carbon content. The organic ligands decompose into amorphous carbon residues during a high-temperature annealing process and hinder the grain growth process. The carbon-rich fine-grain (CRFG) layer generally poses a negative influence on the PV performance of the kesterite solar cell; however, few reports maintain their disposition about CRFG as innocuous. In this review study, a detailed discussion on CRFG is presented, aiming to understand the insights about its formation and impact on the device's performance.