Unprecedented irradiation resistance of nanocrystalline tungsten with equiaxed nanocrystalline grains to dislocation loop accumulation


El-Atwani O., Esquivel E., Aydogan E., Martinez E., Baldwin J. K., Li M., ...Daha Fazla

ACTA MATERIALIA, cilt.165, ss.118-128, 2019 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 165
  • Basım Tarihi: 2019
  • Doi Numarası: 10.1016/j.actamat.2018.11.024
  • Dergi Adı: ACTA MATERIALIA
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.118-128
  • Anahtar Kelimeler: Nanocrystalline, In-situ TEM, Grain boundaries, Dislocation loops, HIGH-ENTROPY ALLOYS, IN-SITU, ION IRRADIATION, MECHANICAL-PROPERTIES, RADIATION TOLERANCE, BOUNDARIES, KINETICS, DAMAGE, EVOLUTION, DIFFUSION
  • Orta Doğu Teknik Üniversitesi Adresli: Hayır

Özet

Nanocrystalline metals are often postulated as irradiation tolerant materials due to higher grain boundary densities. The efficiency of these materials in mitigating irradiation damage is still under investigation. Here, we present an in-situ transmission electron microscopy with ion irradiation study on equiaxed 35 nm grained tungsten (NCW-35 nm) and compare its radiation tolerance, in terms of dislocation loop damage, to several other grades of tungsten with different grain sizes at two temperatures (RT and 1073 K). The NCW-35 nm was shown to possess significant higher radiation tolerance in terms of loop damage. As demonstrated by Kinetic Monte Carlo simulations, at least part of the higher radiation tolerance of the small grains is due to higher interstitial storage (at the grain boundaries) and defect recombination (in the grain interiors) in the small grain material. In addition, experimental observations reveal rapid and efficient dislocation loop absorption by the grain boundaries and this is considered the dominant factor for mass transport to the boundaries during irradiation, enabling the remarkable radiation tolerance of 35 nm grained tungsten. This study demonstrates the possibility of attaining high radiation tolerant materials, in terms of dislocation loop damage, by minimizing grain sizes in the nanocrystalline regime. Published by Elsevier Ltd on behalf of Acta Materialia Inc.