SURFACE STABILITY OF BISMUTH-RUTHENIUM OXIDE ELECTRODES

GOKAGAC G., KENNEDY B.

LANGMUIR, cilt.9, sa.7, ss.1862-1867, 1993 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 9 Sayı: 7
  • Basım Tarihi: 1993
  • Doi Numarası: 10.1021/la00031a039
  • Dergi Adı: LANGMUIR
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1862-1867
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

The effect of anodic polarization on the surface composition of Bi-Ru oxide, Bi2Ru2O7+y, electrodes in acid solution and acid-alcohol solutions has been studied by scanning electron microscopy, energy dispersive X-ray analysis, and X-ray photoelectron spectroscopy. In acidic solution the surface is unstable under either oxidation or reductive conditions, with Bi being lost from the structure. During electrolysis the surface becomes covered with particles of a Bi oxide species.