AN INTERRUPTED IN-SITU METHOD FOR ELECTROCHEMICAL FORMATION OF Mg-Ni INTERMETALLICS


Erden F., KARAKAYA İ. , ERDOĞAN M.

143rd TMS Annual Meeting & Exhibition, California, Amerika Birleşik Devletleri, 16 - 20 Şubat 2014, ss.683-693 identifier

  • Basıldığı Şehir: California
  • Basıldığı Ülke: Amerika Birleşik Devletleri
  • Sayfa Sayıları: ss.683-693

Özet

Mg-Ni system draws attention due to the promising hydrogen storage properties of Mg2Ni. The proposed method involves the use of NiO and MgCl2 in an electrochemical cell to from Mg-Ni intermetallics directly. The electrodeoxidation of NiO was followed by combination of Mg and Ni in molten salt electrolytes. The products were characterized by XRD analysis and SEM examinations. The quantitative results from Rigaku supported by Rietveld Refinement method conducted by Maud showed that more than 50 percent of the input Ni was converted to Mg-Ni intermetallics.