Conducting copolymers of thiophene-functionalized polystyrene

Papila O., Toppare L., Yagci Y., Cianga L.

INTERNATIONAL JOURNAL OF POLYMER ANALYSIS AND CHARACTERIZATION, cilt.9, ss.13-28, 2004 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 9
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1080/10236660490890411
  • Dergi Adı: INTERNATIONAL JOURNAL OF POLYMER ANALYSIS AND CHARACTERIZATION
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.13-28
  • Anahtar Kelimeler: conducting copolymers, pyrrole, LIVING RADICAL POLYMERIZATION, MECHANICAL-PROPERTIES, BLOCK-COPOLYMERS, CHAIN-END, POLYPYRROLE, POLYMERS, PYRROLE
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

The syntheses of conducting copolymers of thiophene-functionalized polystyrene and pyrrole (PS/PPy) were achieved using p-toluene sulfonic acid (PTSA) as the supporting electrolyte via constant potential electrolysis technique. Characterization of the samples was performed by a combination of techniques: cyclic voliammetry (CV), thermogravimetric analysis (TGA), differential scanning colorimetry (DSC), scanning electron microscopy (SEM), NMR, and FT-IR analyses. The conductivities were measured by the four-probe technique.