Decisive role of vacuum-assisted carbonization in valorization of lignin-enriched (Juglans regia-shell) biowaste


Yousaf B. , Liu G., Ali M. U. , Abbas Q., Liu Y., Ullah H., ...More

BIORESOURCE TECHNOLOGY, vol.323, 2021 (Journal Indexed in SCI) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 323
  • Publication Date: 2021
  • Doi Number: 10.1016/j.biortech.2020.124541
  • Title of Journal : BIORESOURCE TECHNOLOGY
  • Keywords: Vacuum-assisted pyrolysis, Waste valorization, Lignin enriched biomass, Biochar, Bio-oil

Abstract

Bioenergy is considered a sustainable substitute to fossil-fuel resources and the development of a prudent combination of renewable and innovative conversion technologies are essential for the valorization and effective conversion of biowaste to value-added commodities. Here, a negative pressure-induced carbonization process was proposed for the valorization of lignin-enriched biowaste precursor to bio-oil and environmental materials (biochar) at various temperatures. The high heating values (HHV) of the as-prepared biochars from the lignin enriched precursor under negative pressure (low-medium vacuum) were within 25.9-31.5 MJ/kg, which matched satisfactorily to the commercial charcoal. Whereas, the bio-oils produced from the lignin enriched precursor under vacuum conditions was a blend of complex aromatic and straight-chain hydro-carbons, including aldehyde, ketone, phenol, and furans, exhibiting ability as potential heating-oil with HHV within 21.2-28.2 MJ/kg. Moreover, the biochars produced under vacuum environments at higher temperature showed greater stability (22.5-35.9%) than those produced under N-2 atmosphere.