A simple one-pot synthesis of methyltribromosilane


Pitcher M. W. , Bianconi P. A.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.182, sa.8, ss.1819-1822, 2007 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 182 Konu: 8
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1080/10426500701323382
  • Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
  • Sayfa Sayıları: ss.1819-1822

Özet

A simple one-pot synthesis of methyltribromosilane has been developed. The straightforward reaction of a slight excess of silicon tetrabromide with one equivalent of powdered methyllithium in refluxing pentane produces methyltribromosilane in high yields.