A facile synthesis of various butenolides

Tanyeli C., CALİSKAN Z. Z.

SYNTHETIC COMMUNICATIONS, cilt.30, sa.16, ss.2855-2862, 2000 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 30 Sayı: 16
  • Basım Tarihi: 2000
  • Doi Numarası: 10.1080/00397910008087436
  • Dergi Adı: SYNTHETIC COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2855-2862
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

The synthesis of alpha'-acyloxy-alpha,beta-unsaturated cyclic ketones from the corresponding alpha,beta-unsaturated cyclic ketones by using manganese (III) acetate in combination with 2-chloropropionic acid followed by subsequent Arbuzov and intramolecular Horner-Emmons cyclization reactions provided a convenient synthetic pathway to various butenolides 4a-d.