Investigation of solid solution of ZrP2O7-Sr2P2O7

Seyyidoglu S., Oezenbas M., Yazici N., Yilmaz A.

JOURNAL OF MATERIALS SCIENCE, cilt.42, sa.15, ss.6453-6463, 2007 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 42 Sayı: 15
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1007/s10853-006-0673-8
  • Dergi Adı: JOURNAL OF MATERIALS SCIENCE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.6453-6463
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

In this study, ZrP2O7 was synthesized by the solid state reaction of ZrO2 and NH4H2PO4 at 900 degrees C. Then, in set 1; 10, 5, 1, 0.5, 0.1, 0.05, 0.03% previously prepared Sr2P2O7 were doped into ZrP2O7, and Sr2P2O7 slightly affect the unit cell parameter of cubic ZrP2O7 (a = 8.248(6)-8.233(8) angstrom). The reverse of this process was also applied to Sr2P2O7 system (set 2). ZrP2O7 changes the unit cell parameters of orthorhombic Sr2P2O7 in between a = 8.909(5)-8.877(5) angstrom, b = 13.163(3)-13.12(1) angstrom, and c = 5.403(2)-5.386(4) angstrom. Analysis of the vibrations of the P2O74- ion and approximate band assignments for IR and Raman spectra are also reported in this work. Some coincidences in infrared and Raman spectra both sets were found and strong P-O-P bands were observed. Surface morphology, EDX analysis, and thermoluminescence properties of both sets were given the first time in this paper.