THE OXIDATION OF BETA-ALKOXYCYCLOPENTENONES AND BETA-ALKOXYCYCLOHEXENONES TO ALPHA'-ACYLOXY DERIVATIVES USING MANGANESE(III) ACETATE IN COMBINATION WITH CARBOXYLIC-ACIDS


DEMIR A. , SAYRAC T., WATT D.

SYNTHESIS-STUTTGART, no.12, pp.1119-1121, 1990 (Journal Indexed in SCI) identifier

  • Publication Type: Article / Article
  • Publication Date: 1990
  • Title of Journal : SYNTHESIS-STUTTGART
  • Page Numbers: pp.1119-1121

Abstract

The alpha-oxidation of cyclic derivatives of beta-alkoxy-alpha, beta-unsaturated ketones using manganese (III) acetate in the presence of various carboxylic acids provided a convenient synthesis of 5-acyloxy-3-alkoxy-2-cyclopentenones and 6-acyloxy-3-alkoxy-2-cyclohexenones.