THE OXIDATION OF BETA-ALKOXYCYCLOPENTENONES AND BETA-ALKOXYCYCLOHEXENONES TO ALPHA'-ACYLOXY DERIVATIVES USING MANGANESE(III) ACETATE IN COMBINATION WITH CARBOXYLIC-ACIDS


DEMIR A. , SAYRAC T., WATT D.

SYNTHESIS-STUTTGART, sa.12, ss.1119-1121, 1990 (SCI İndekslerine Giren Dergi) identifier

  • Basım Tarihi: 1990
  • Dergi Adı: SYNTHESIS-STUTTGART
  • Sayfa Sayıları: ss.1119-1121

Özet

The alpha-oxidation of cyclic derivatives of beta-alkoxy-alpha, beta-unsaturated ketones using manganese (III) acetate in the presence of various carboxylic acids provided a convenient synthesis of 5-acyloxy-3-alkoxy-2-cyclopentenones and 6-acyloxy-3-alkoxy-2-cyclohexenones.