Synthesis and characterization of graft copolymers of poly(2-(N-pyrrolyl)ethylvinylether) and polypyrrole

Kalaycioglu E., Toppare L., Yagci Y.

SYNTHETIC METALS, cilt.108, sa.1, ss.1-7, 2000 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 108 Sayı: 1
  • Basım Tarihi: 2000
  • Doi Numarası: 10.1016/s0379-6779(99)00147-2
  • Dergi Adı: SYNTHETIC METALS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1-7
  • Anahtar Kelimeler: poly(2-(N-pyrrolyl)ethylvinylether), electrochemical grafting, POLY(METHYL METHACRYLATE), IRON CHLORIDE, COMPOSITES, POLYVINYL-CHLORIDE), POLYMERIZATION, NITROMETHANE, PYRROLE
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

Poly(2-(N-pyrrolyl)ethylvinylether) (poly(2-NEVE)) was synthesized from poly(2-chloroethylvinylether) (poly(2-CEVE)) via phase catalysis reaction. Graft copolymers of PPy/poly(2-NEVE) were synthesized by electrochemical methods. The chemical structure of poly(2-NEVE) was investigated by several spectroscopic and thermal methods. Graft copolymers were characterized by means of FTIR, Differential Scanning Calorimetry (DSC), Thermal Gravimetry Analysis (TGA), Scanning Electron Microscope (SEM). Conductivities of graft copolymers were measured via four-probe technique. (C) 2000 Elsevier Science S.A. All rights reserved.