PLE catalysed enantiomeric separation of various (+/-)-6-acetoxy-alpha,beta-unsaturated cyclic ketones


Tanyeli C. , Sezen B., Dikici E., Fleischhauer J., Repges C., Wang Y., ...Daha Fazla

ENANTIOMER, cilt.6, sa.4, ss.219-227, 2001 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 6 Konu: 4
  • Basım Tarihi: 2001
  • Dergi Adı: ENANTIOMER
  • Sayfa Sayıları: ss.219-227

Özet

Various (+/-)-6-acetoxy-alpha,beta -unsaturated cyclic ketones were resolved by PLE catalysed hydrolysis to afford enantiomerically enriched 6-hydroxy derivatives with 85-98% e.e. The absolute configuration of 6-hydroxy-alpha,beta -unsaturated cyclic ketones were determined via CD measurements.