Click-Type Synthesis of Homoconjugated Push-Pull Chromophores: Computational Investigation of Optical and Nonlinear Optical (NLO) Properties

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Inyurt F. C., Mammadova F., DENGİZ Ç.

SYNOPEN, cilt.7, sa.1, ss.1-7, 2023 (ESCI) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 7 Sayı: 1
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1055/a-2004-6344
  • Dergi Adı: SYNOPEN
  • Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI)
  • Sayfa Sayıları: ss.1-7
  • Anahtar Kelimeler: triazene, nonlinear optics, [2+2] cycloaddition, homoconjugation, donor-acceptor systems, intramolecular charge transfer, DENSITY-FUNCTIONAL THEORY, ACCEPTOR, CHEMISTRY, MOLECULES, TRIAZENE, ANALOGS, DFT
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

Homoconjugated push-pull chromophores were obtained by an efficient, click-type formal [2+2] cycloaddition. With these short synthetic transformations, complex chromophore structures were achieved in a single step without any by-product formation. Significant second-order optical nonlinearities have been calculated for the synthesized compounds.