Cu doping of Sb2Se3 thin films via thermal evaporation: Tailoring structural and optical properties for enhanced photovoltaic performance

Isik M., Surucu O., Bektas T., PARLAK M.

Optical Materials, cilt.167, 2025 (SCI-Expanded, Scopus) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 167
  • Basım Tarihi: 2025
  • Doi Numarası: 10.1016/j.optmat.2025.117362
  • Dergi Adı: Optical Materials
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Aerospace Database, Applied Science & Technology Source, Chimica, Communication Abstracts, Compendex, Computer & Applied Sciences, INSPEC
  • Anahtar Kelimeler: Band gap tuning, Optical properties, Optoelectronic applications, Photovoltaic materials
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

In this study, Cu-doped Sb2Se3 thin films were successfully grown using the thermal evaporation method, and their structural and optical properties were systematically investigated. Three different samples with thickness of ∼400 nm were analyzed: undoped, 1 %, and 2 % Cu-doped Sb2Se3. X-ray diffraction (XRD) analysis revealed well-defined peaks, confirming the orthorhombic crystalline nature of the films. Scanning electron microscopy (SEM) images showed a uniform surface morphology without any significant defects. The optical properties were examined through transmission measurements. The band gap energy determined by Tauc analysis decreased from 1.27 to 1.21 eV as the Cu doping increased from 0 % to 2 %, indicating that Cu incorporation modifies the electronic structure of Sb2Se3. Similarly, Urbach energy increased from 0.148 to 0.168 eV depending on Cu content, suggesting a rise in localized states due to increased structural disorder. These findings demonstrate that Cu doping influences the electronic structure and defect states of Sb2Se3, which is crucial for optimizing its performance in photovoltaic and optoelectronic applications.