Reactions of 2-substituted epichlorohydrins


Tanyeli C. , Demir A. , Akhmedov I., Ozgul E., Kandemir C.

SYNTHETIC COMMUNICATIONS, cilt.26, ss.2967-2980, 1996 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 26 Konu: 16
  • Basım Tarihi: 1996
  • Doi Numarası: 10.1080/00397919608004600
  • Dergi Adı: SYNTHETIC COMMUNICATIONS
  • Sayfa Sayıları: ss.2967-2980

Özet

2-Substituted epichlorohydrins have been synthesized by starting with 1,2-dichloro acetone and various alkyl and aryl halides via dichlorohydrins followed by cyclization. The reactive 2-substituted epichlorohydrins were subjected to nucleophilic attacking of azide and cyanide ions to afford corresponding beta-azido alcohols and alpha,beta-unsaturated nitriles.