Reactions of 2-substituted epichlorohydrins

Tanyeli, CİHANGİR; Demir, AYHAN; Akhmedov, IM; Ozgul, E; Kandemir, CG

doi:10.1080/00397919608004600

Reactions of 2-substituted epichlorohydrins

Tanyeli C., Demir A., Akhmedov I., Ozgul E., Kandemir C.

SYNTHETIC COMMUNICATIONS, vol.26, no.16, pp.2967-2980, 1996 (SCI-Expanded, Scopus)

Publication Type: Article / Article
Volume: 26 Issue: 16
Publication Date: 1996
Doi Number: 10.1080/00397919608004600
Journal Name: SYNTHETIC COMMUNICATIONS
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Page Numbers: pp.2967-2980
Middle East Technical University Affiliated: Yes

Abstract

2-Substituted epichlorohydrins have been synthesized by starting with 1,2-dichloro acetone and various alkyl and aryl halides via dichlorohydrins followed by cyclization. The reactive 2-substituted epichlorohydrins were subjected to nucleophilic attacking of azide and cyanide ions to afford corresponding beta-azido alcohols and alpha,beta-unsaturated nitriles.