Ring expansion in the coupling of Fischer-carbene complexes with 1-alkynyl-1-hydroxy cyclic compounds
TETRAHEDRON, cilt.57, sa.24, ss.5097-5107, 2001 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 57 Sayı: 24
- Basım Tarihi: 2001
- Doi Numarası: 10.1016/s0040-4020(01)00359-3
- Dergi Adı: TETRAHEDRON
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.5097-5107
- Orta Doğu Teknik Üniversitesi Adresli: Evet
Özet
The coupling of a variety of transition metal-carbene complexes with alkynols has been studied. In many cases, the intermediate vinylcarbene complexes formed in this reaction undergo a ring expansion to afford cyclic ketone derivatives. This scope and limit of this process is explored. (C) 2001 Elsevier Science Ltd. All rights reserved.