Room temperature aerobic Suzuki cross-coupling reactions in DMF/water mixture using zeolite confined palladium(0) nanoclusters as efficient and recyclable catalyst


DURAP F., Rakap M., AYDEMİR M., ÖZKAR S.

APPLIED CATALYSIS A-GENERAL, vol.382, no.2, pp.339-344, 2010 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 382 Issue: 2
  • Publication Date: 2010
  • Doi Number: 10.1016/j.apcata.2010.05.021
  • Title of Journal : APPLIED CATALYSIS A-GENERAL
  • Page Numbers: pp.339-344

Abstract

Herein we report the use of zeolite confined palladium(0) nanoclusters as efficient and recyclable catalyst for Suzuki cross-coupling reactions of aryl bromides with phenylboronic acid. Zeolite confined palladium(0) nanoclusters are highly active catalyst for the Suzuki cross-coupling reactions under mild conditions (room temperature, in air) in DMF/water (1:9) mixture. A variety of aryl bromides undergo Suzuki cross-coupling with phenylboronic acid with quantitative GC yields of biaryl derivatives. Recycling experiments showed that zeolite confined palladium(0) nanoclusters can be used as recyclable catalyst in the Suzuki cross-coupling reactions. (c) 2010 Elsevier B.V. All rights reserved.