ELECTROINITIATED POLYMERIZATION OF MALEIC-ANHYDRIDE BY DIRECT ELECTRON-TRANSFER


AKBULUT U. , HACIOGLU B.

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, cilt.29, ss.219-224, 1991 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 29 Konu: 2
  • Basım Tarihi: 1991
  • Doi Numarası: 10.1002/pola.1991.080290209
  • Dergi Adı: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
  • Sayfa Sayıları: ss.219-224

Özet

Controlled potential electrolysis was employed to accomplish homopolymerization of maleic anhydride, by direct electron transfer. The solvent used in the polymerization studies was acetonitrile-dimethylformamide mixture (1:1) with the supporting electrolyte tetrabutylammonium tetra fluoroborate. A brown paramagnetic polymer was obtained from the catholyte, upon electroreduction of monomer.