Bis(2-pyridyl)-substituted boratriazaindacene as an NIR-emitting chemosensor for Hg(II)


Coskun A., Yilmaz M. D. , Akkaya E. U.

ORGANIC LETTERS, cilt.9, sa.4, ss.607-609, 2007 (SCI İndekslerine Giren Dergi) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 9 Konu: 4
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1021/ol062867t
  • Dergi Adı: ORGANIC LETTERS
  • Sayfa Sayıları: ss.607-609

Özet

Aryl-substituted boratriazaindacenes (Aza-Bodipy's) are a new class of dyes with long wavelength absorption and emissions. We now report the first application of these dyes in metal ion sensing. 2-Pyridyl substituents at positions 1 and 7 create a well-defined pocket for metal ion binding. The chemosensor described here is selective for Hg(II) ions, and both absorption and emission spectra display large changes that would allow ratiometric sensing.