Controlled synthesis of block copolymers containing side chain thiophene units and their use in electrocopolymerization with thiophene and pyrrole


Yilmaz F., Sel O., Guner Y., Toppare L. , Hepuzer Y., Yagci Y.

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, ss.401-418, 2004 (SCI İndekslerine Giren Dergi) identifier identifier

  • Basım Tarihi: 2004
  • Doi Numarası: 10.1081/ma-120028475
  • Dergi Adı: JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
  • Sayfa Sayıları: ss.401-418

Özet

This paper reports on the synthesis of conducting polypyrrole and polythiophene grafted block copolymers of methylmethacrylate (MMA) and 3-methylthienylmethacrylate (MTM) by a multi-step process. For this purpose, block copolymers of MMA and MTM were prepared by controlled radical polymerization using 1,1-diphenylethene (DPE). Subsequently, polypyrrole and polythiophene sequences were grafted onto these block copolymers by constant potential electrolysis.