Manganese(III) acetate oxidation of some ketones in the presence of 3-chloropropionic acid and theoretical investigation of the products

Akdag, AKIN; Tarhan, O; Turker, L

doi:10.1016/s0166-1280(01)00567-x

Manganese(III) acetate oxidation of some ketones in the presence of 3-chloropropionic acid and theoretical investigation of the products

Atıf İçin Kopyala

Akdag A., Tarhan O., Turker L.

JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, cilt.571, ss.201-206, 2001 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 571
Basım Tarihi: 2001
Doi Numarası: 10.1016/s0166-1280(01)00567-x
Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.201-206
Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

Manganese(III) acetate oxidation of some ketones in the presence of 3-chloropropionic acid was carried out. The products were characterized. The experimental results were compared with the theoretical ones which was based on AM1 (UHF) type semi-empirical calculations. The theoretical results disfavor any mechanism solely based on radical stability involving radicals originating from the reactants. (C) 2001 Elsevier Science B.V. All rights reserved.