Industrial production leads to toxic heavy metal pollution in water bodies. Copper is one of the examples that requires removal from effluents before being discharged. It is difficult and sometimes very expensive to remove toxic heavy metals by conventional treatment techniques. This study aims to remove copper by the use of bacterial alginate as a non-conventional technique. Bacterial alginates (natural polymers composed of mannuronic and guluronic acid monomers) were synthesized by Azotobacter vinelandii ATCC (R) 9046 in a laboratory fermentor under controlled environmental conditions. The alginates produced, with a range of different characteristics in terms of monomer distribution and viscosity, were investigated for maximum copper uptake capacities. The average copper uptake capacities of alginates produced were found to be about 1.90 mmol/L Cu2+/g alginate. Although the GG-block amount of alginates was varied from 12 to 87% and culture broth viscosities were changed within the range of 1.47 and 14 cP, neither the block distribution nor viscosities of alginate samples considerably affected the copper uptake of alginates.