Ethyl (E)-2-furyl-2-(hydroxyimino)acetate


Ulku D., Tahir M., Demir A. , Aksoy-Cam H.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, vol.54, pp.94-95, 1998 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 54
  • Publication Date: 1998
  • Doi Number: 10.1107/s0108270197009852
  • Title of Journal : ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
  • Page Numbers: pp.94-95

Abstract

In the title compound, C8H9NO4, the hydrogen bonds between the oxime O atoms and the N and O atoms of the neighbouring asymmetric unit result in the dimerization of the molecules, with D...A distances of 2.774 (3) and 3.144 (3) Angstrom for O-H ... N and O-H ... O, respectively. The hydrogen-bridged centrosymmetric dimers are cross-linked via additional weaker intermolecular hydrogen bonds between the CH3 group and the other O atom of the dimer, forming a polymeric network. The D...A distance of this second-order interaction (C-H ... O) is 3.450 (2) Angstrom. Structure analysis indicates that the oxime is in an E configuration. The whole molecule is planar, with a maximum deviation from the least-squares plane of 0.104 (2) Angstrom.