Synthesis and electroactivity of pyrrole end-functionalized poly(2-methyl-2-oxazoline)

Cirpan A., ALKAN S., TOPPARE L. K., DAVID G., YAGCI Y.

EUROPEAN POLYMER JOURNAL, cilt.37, sa.11, ss.2225-2229, 2001 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 37 Sayı: 11
  • Basım Tarihi: 2001
  • Doi Numarası: 10.1016/s0014-3057(01)00103-3
  • Dergi Adı: EUROPEAN POLYMER JOURNAL
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2225-2229
  • Anahtar Kelimeler: macromonomer, pyrrole functionalization, poly(2-methyl-2-oxazoline), BLOCK-COPOLYMERS, POLY(METHYL METHACRYLATE), GRAFT-COPOLYMERS, POLYPYRROLE, POLYTETRAHYDROFURAN, IMMOBILIZATION, INVERTASE, MATRICES, FILMS
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

Poly (2-methyl-2-oxazoline) (PMeOZO) with pyrrole end groups was synthesized by cationic ring polymerization of 2-methyl-2-oxazoline initiated by benzyl bromide and subsequent modification of the halide end group. The structure and electroactivity of the macromonomer thus obtained were confirmed by spectral analysis and cyclic voltametry, respectively. The posssibility of chemical and electrochemical graft copolymerization of PMeOZO with pyrrole was also studied. (C) 2001 Elsevier Science Ltd. All rights reserved.