Kinetics of trona sulfur dioxide reaction
CHEMICAL ENGINEERING AND PROCESSING, cilt.40, sa.1, ss.13-18, 2001 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 40 Sayı: 1
- Basım Tarihi: 2001
- Doi Numarası: 10.1016/s0255-2701(00)00104-5
- Dergi Adı: CHEMICAL ENGINEERING AND PROCESSING
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.13-18
- Orta Doğu Teknik Üniversitesi Adresli: Hayır
Özet
One of the most efficient methods of desulfurization of flue gases involves the reaction of SO2 with activated soda in a dry system. In this work, reactivities of activated soda produced from trona by direct calcination and by spray drying of trona solution were compared and a reaction mechanism was proposed. Due to the textural variations of the solid during the reaction and due to the increased significance of adsorption of SO2, at low temperatures, a two step reaction behavior was observed. Predictions from the deactivation model gave satisfactory agreement with the experimental data. (C) 2001 Elsevier Science B.V. All rights reserved.