Synthesis of ZIF-8 from recycled mother liquors

Demir N. K., Topuz B., YILMAZ L., KALIPÇILAR H.

MICROPOROUS AND MESOPOROUS MATERIALS, cilt.198, ss.291-300, 2014 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 198
  • Basım Tarihi: 2014
  • Doi Numarası: 10.1016/j.micromeso.2014.07.052
  • Dergi Adı: MICROPOROUS AND MESOPOROUS MATERIALS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.291-300
  • Anahtar Kelimeler: ZIF-8, MOP, Synthesis, Mother liquor, Recycling, METAL-ORGANIC FRAMEWORKS, ZEOLITIC IMIDAZOLATE FRAMEWORKS, MIXED-MATRIX MEMBRANES, ROOM-TEMPERATURE SYNTHESIS, CRYSTAL-GROWTH, SEPARATION, CRYSTALLIZATION, TRANSFORMATION, NANOCRYSTALS, DIFFRACTION
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

The effect of the methanol/Zn(NO3)(2) molar ratio on the particle size, BET surface area and on the rate of the crystallization have been studied. The use of excess methanol leads to a decrease in particle size and rate of crystallization. Crystals grown from solutions with methanol/Zn(NO3)(2) molar ratios of 1043 and 87 are 60 and 600 nm based on SEM images, respectively.