Silver-Catalyzed Formal Inverse Electron-Demand Diels-Alder Reaction of 1,2-Diazines and Siloxy Alkynes


TÜRKMEN Y. E., Montavon T. J., Kozmin S. A., Rawal V. H.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, cilt.134, sa.22, ss.9062-9065, 2012 (SCI-Expanded, Scopus)

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 134 Sayı: 22
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1021/ja302537j
  • Dergi Adı: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Index Chemicus (IC), Current Chemical Reactions (CCR)
  • Sayfa Sayıları: ss.9062-9065
  • Orta Doğu Teknik Üniversitesi Adresli: Hayır

Özet

A highly effective silver-catalyzed formal inverse electron-demand Diets Alder reaction of 1,2-diazines and siloxy alkynes has been developed. The reactions provide ready access to a wide range of siloxy naphthalenes and anthracenes, which are formed in good to high yields, under mild reaction conditions, using low catalyst loadings.