Diamminebis(2,4,6-trichlorophenolato)-copper(II)


Gokagac G., Tatar L., Kisakurek D., Ulku D.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, vol.55, pp.1413-1416, 1999 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 55
  • Publication Date: 1999
  • Doi Number: 10.1107/s0108270199006447
  • Title of Journal : ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
  • Page Numbers: pp.1413-1416

Abstract

The crystal structure of the title compound, [Cu(C6H2Cl3)(2)(NH3)(2)], has been determined by X-ray diffraction. The title monomeric centrosymmetric Cu-II complex crystallizes in the monoclinic system. The CuO2N2 coordination sphere is trans-planar [Cu-O1 = 1.946(2) and Cu-N1 = 1.984(2) Angstrom], with the fifth and sixth coordination sites blocked by Cl atoms fi om the phenoxide ions [Cu-Cl1 = 2.982(1) Angstrom] to form a tetragonally elongated octahedral structure for CuO2N2Cl2 coordination. Intermolecular hydrogen bonds hold the complex molecules together in a one-dimensional chain.