A novel multielectrochromic copolymer based on 1-(4-nitrophenyl)-2,5-di(2-thienyl)-1H-pyrrole and EDOT

Varis S., Ak M., Akhmedov I. M., Tanyeli C., Toppare L.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, vol.603, no.1, pp.8-14, 2007 (SCI-Expanded) identifier identifier


Copolymer of 1-(4-nitrophenyl)-2,5-di(2-thienyl)-1H-pyrrole (NTP) with 3,4-ethylene dioxythiophene (EDOT) was electrochemically synthesized and characterized. Resulting copolymer film has distinct electrochromic properties. It has five different colors (light red, red, light grey, green, and blue). At the neutral state lambda(max) x value due to the pi-pi* transition was found to be 550 nm and E-g was calculated as 1.6 eV. Double potential step chronoamperometry experiment shows that copolymer film has good stability, fast switching time (1.2 s) and high optical contrast (42%).