A general and efficient synthesis of nitrogen-substituted ferrocenes

Ozcubukcu S., Schmitt E., Leifert A., Bolm C.

SYNTHESIS-STUTTGART, no.3, pp.389-392, 2007 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Publication Date: 2007
  • Doi Number: 10.1055/s-2006-958961
  • Journal Name: SYNTHESIS-STUTTGART
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.389-392
  • Keywords: copper, cross-coupling, ferrocene, heterocycle, Ullmann coupling, SULFOXIMINES, LIGANDS, CATALYSIS, CARBENES, OXIDE
  • Middle East Technical University Affiliated: No

Abstract

Copper(l) iodide mediated Ullmann-type coupling reactions of iodoferrocene and 1,1'-diiodoferrocene has been used to synthesize N-substituted ferrocenes that are difficult to obtain by classical methods. In this manner, a range of Fc-[N]-R-type compounds have been prepared in moderate to good yields.