Synthesis of conducting graft copolymers of 2-(N-pyrrolyl)ethylvinyl ether with pyrrole


Bengu B., Toppare L. , Kalaycioglu E.

DESIGNED MONOMERS AND POLYMERS, vol.4, no.1, pp.53-65, 2001 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 4 Issue: 1
  • Publication Date: 2001
  • Doi Number: 10.1163/156855501744865
  • Title of Journal : DESIGNED MONOMERS AND POLYMERS
  • Page Numbers: pp.53-65

Abstract

2-(N-pyrrolyl)ethylvinyl ether (2-NEVE) was synthesized from 2-chloroethylvinyl ether (2-CEVE) via a phase catalysis reaction. Cyclic voltammetric studies were carried out to check for the electroactivity of 2-NEVE. Poly(2-(N-pyrrolyl)ethylvinyl ether) [poly(2-NEVE)] was synthesized via chemical methods. Graft copolymers of pyrrole and 2-NEVE were synthesized by electrochemical methods. The chemical structures of 2-NEVE and poly(2-NEVE) were investigated by several spectroscopic methods. Graft copolymers were characterized by means of FTIR, scanning electron microscopy (SEM). differential scanning calorimetry (DSC), and thermal gravimetric analysis (TGA). The conductivities of the graft copolymers were measured via a four-probe technique.