A Five Layer One-Dimensional PEMFC Model with Detailed Electrode Kinetics


Ficicilar B., Eroglu I. , Nguyen T. V.

10th Polymer Electrolyte Fuel Cells Symposium (PEFC) Conducted Under the Auspices of the 218th Meeting of the Electrochemical-Society (ECS), Nevada, United States Of America, 01 October 2010, vol.33, pp.1515-1516 identifier identifier

  • Publication Type: Conference Paper / Full Text
  • Volume: 33
  • Doi Number: 10.1149/1.3484644
  • City: Nevada
  • Country: United States Of America
  • Page Numbers: pp.1515-1516

Abstract

In this study, a non-isothermal, two-phase, one-dimensional, and steady state proton exchange membrane (PEM) fuel cell model is developed to investigate the detailed electrode kinetics in the anode and cathode catalytic regions and the effects of these reaction mechanisms on the performance of a PEM fuel cell. Langmuir-Butler-Volmer (LBV) type reaction rate expressions are suggested for both anode and cathode electrochemical reactions. A two-phase energy balance approach is used to catch the thermal transport phenomena in cases when there is a significant temperature difference between the fuel cell temperature and the reactants inlet temperatures like during cold start-up.