Characterization and Kinetics of Siberian and Tatarstan Regions Crude Oils Using Differential Scanning Calorimetry

Varfolomeev M. A., Rakipov I. T., Isakov D. R., Nurgaliev D. K., KÖK M. V.

PETROLEUM SCIENCE AND TECHNOLOGY, cilt.33, sa.8, ss.865-871, 2015 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 33 Sayı: 8
  • Basım Tarihi: 2015
  • Doi Numarası: 10.1080/10916466.2015.1021011
  • Dergi Adı: PETROLEUM SCIENCE AND TECHNOLOGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.865-871
  • Anahtar Kelimeler: crude oil, thermal analysis, differential scanning calorimetry, kinetics, in-situ combustion, THERMAL-BEHAVIOR, OXIDATION, FRACTIONS
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

In this study, nonisothermal kinetics and thermal analysis of Siberian and Tatarstan regions crude oils is studied by differential scanning calorimetry (DSC) at different heating rates. DSC curves revealed two reaction regions in the temperature range of 20-600 degrees C, known as low and high temperature oxidation, respectively. Three different kinetic methods (ASTM, Borchardt and Daniels, and Roger and Morris) were used to determine the kinetic parameters of the samples and it was observed that the activation energy values are varied.