Metal- and Base-Free Combinatorial Reaction for C-Acylation of 1,3-Diketo Compounds in Vegetable Oil: The Effect of Natural Oil


Menges N., ŞAHİN E.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, vol.2, no.2, pp.226-230, 2014 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 2 Issue: 2
  • Publication Date: 2014
  • Doi Number: 10.1021/sc400281h
  • Title of Journal : ACS SUSTAINABLE CHEMISTRY & ENGINEERING
  • Page Numbers: pp.226-230

Abstract

C-acylation of 1,3-diketo compounds has been done successfully employing 1,3 diketo compounds, oxalyl chloride, and phenol derivatives through metal, base, and toxic solvent-free protocol. Dioxinone ring-bearing 1,3,3' tricarbonyl moiety was also obtained in the same conditions using salicyl aldehyde. All reactions were carried out in vegetable oil.