Self-condensation reactions of acyl phosphonates: synthesis of tertiary O-protected alpha-hydroxyphosphonates

EYMUR S., Gollu M., Demir A. S.

TURKISH JOURNAL OF CHEMISTRY, cilt.38, sa.1, ss.164-171, 2014 (SCI-Expanded, Scopus, TRDizin) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 38 Sayı: 1
  • Basım Tarihi: 2014
  • Doi Numarası: 10.3906/kim-1306-7
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.164-171
  • Anahtar Kelimeler: Acyl phosphonates, tertiary alpha-hydroxy phosphonates, phosphonate-phosphate rearrangement, ENANTIOSELECTIVE SYNTHESIS, ASYMMETRIC-SYNTHESIS, HYDROXY PHOSPHONATES, ANION EQUIVALENTS, DERIVATIVES, INHIBITORS, STATE, ACYLPHOSPHONATES, OXIDATION
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

The self-condensation reaction of benzoyl dialkyl phosphonates was developed using cyanide ion as catalyst, affording versatile tertiary O-protected alpha-hydroxy phosphonates in moderate yield.