AN EFFICIENT BUTENOLIDE ANNULATION VIA ALPHA'-CHLOROACETOXYLATION OF ENONES USING MANGANESE(III) ACETATE AND CHLOROACETIC ACID

DEMIR, AS; AKGUN, H; TANYELI, CİHANGİR; SAYRAC, T; WATT, DS

AN EFFICIENT BUTENOLIDE ANNULATION VIA ALPHA'-CHLOROACETOXYLATION OF ENONES USING MANGANESE(III) ACETATE AND CHLOROACETIC ACID

DEMIR A., AKGUN H., TANYELI C., SAYRAC T., WATT D.

SYNTHESIS-STUTTGART, sa.9, ss.719-721, 1991 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Basım Tarihi: 1991
Dergi Adı: SYNTHESIS-STUTTGART
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.719-721
Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

The alpha'-chloroacetoxylation of alpha,-beta-unsaturated ketones using manganese(III) acetate and chloroacetic acid followed by Arbuzov reaction and intramolecular Horner-Emmons olefination provided a convenient synthesis of annulated 2-buten-4-olides.