A stable carbonyl-pyrazine-metal(0) complex: Synthesis and characterization of cis-tetracarbonylpyrazinetrimethylphosphitetungsten(0)

Alper F., Kayran C., Ozkar S.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, cilt.691, sa.12, ss.2734-2738, 2006 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 691 Sayı: 12
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1016/j.jorganchem.2006.02.005
  • Dergi Adı: JOURNAL OF ORGANOMETALLIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2734-2738
  • Anahtar Kelimeler: pyrazine, carbonyl, tungsten, trimethylphosphite, synthesis, bimetallic complex, equilibrium constant, ORGANOMETALLIC HETEROCYCLIC CHEMISTRY, NUCLEAR MAGNETIC RESONANCE, METAL-CARBONYL-COMPLEXES, RAY CRYSTAL-STRUCTURES, ELECTROCHEMICAL PROPERTIES, COPPER(II) COMPLEXES, LINEAR-CHAIN, PYRAZINE, DERIVATIVES, POLYMERS
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

Pentacarbonylpyrazinetungsten(0), (CO)(5)W(pyz), is not stable in solution in polar solvents such as acetone or dichloromethane and undergoes conversion to a bimetallic complex, (CO)(5)W(pyz)W(CO)(5) plus free pyrazine. These three species exist at equilibrium. Using the quantitative H-1 NMR spectroscopy, the equilibrium constant could be determined to be K-eq = (5.9 +/- 0.8) x 10(-2) at 25 degrees C. Introducing a second pyrazine ligand into the molecule does not stabilize the complex, as CiS-W(CO)(4)(pyz)(2) was found to be less stable than W(CO)(5)(pyz) and, therefore, could not be isolated. However, introducing trimethylphosphite as a donor ligand into the complex leads to the stabilization of the carbonyl-pyrazine-metal(0) complexes, as shown by the synthesis Of CiS-W(CO)(4)[P(OCH3)(3)](pyz). This complex could be isolated from the reaction of the photogenerated W(CO)(4)[P(OCH3)(3)](tetrahydrofuran) with trimethylphosphite upon mixing for 2 h at 10 degrees C in tetrahydrofuran and characterized by elemental analysis, IR, MS, H-1, C-13 and P-31 NMR spectroscopy. (c) 2006 Elsevier B.V. All rights reserved.