Magnetic ordering in two ferromagnetic sublattices of two mixed-valence iron(II)-iron(III) metal formate frameworks

Yurtseven H., Dogan E. K.

MATERIALS RESEARCH BULLETIN, vol.119, 2019 (Peer-Reviewed Journal) identifier identifier

  • Publication Type: Article / Article
  • Volume: 119
  • Publication Date: 2019
  • Doi Number: 10.1016/j.materresbull.2019.110572
  • Journal Indexes: Science Citation Index Expanded, Scopus
  • Keywords: Magnetic phase transition, Magnetization, Molecular field theory, Mixed-valence iron (II)-iron (III) MOFs, TEMPERATURE, MN, FE


Temperature dependence of magnetization (M) is calculated for two mixed-valence iron(II) - iron(III) metal formate frameworks (MOFs) with the two ferromagnetic sublattices below T-comp (compensation temperature) at 100 Oe by the molecular field theory. Temperature dependence of magnetization (M-T) is analyzed between T(comp )and T-ord = 39K (ordering temperature) by the power-law formula using the literature data for those compounds. Power-law analysis is also carried out for the field dependence of magnetization (M-H) for 0 < H < 50 Oe interval (T = 2 K) by using the literature data for those MOFs. From both power-law analyses, the temperature-induced (beta) and field-induced (delta) critical exponents for magnetization are deduced for the compounds studied.