Morphochemical investigation on the enrichment and transformation of hazardous elements in ash from waste incineration plants

Ali M. U. , Liu Y., YOUSAF B., Wong M. H. , Li P., Liu G., ...More

Science of the Total Environment, vol.828, 2022 (Peer-Reviewed Journal) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 828
  • Publication Date: 2022
  • Doi Number: 10.1016/j.scitotenv.2022.154490
  • Journal Name: Science of the Total Environment
  • Journal Indexes: Science Citation Index Expanded, Scopus, Academic Search Premier, PASCAL, Aerospace Database, Analytical Abstracts, Aqualine, Aquatic Science & Fisheries Abstracts (ASFA), BIOSIS, Biotechnology Research Abstracts, CAB Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, EMBASE, Environment Index, Food Science & Technology Abstracts, Geobase, Greenfile, MEDLINE, Metadex, Pollution Abstracts, Public Affairs Index, Veterinary Science Database, Civil Engineering Abstracts
  • Keywords: Migration mechanism, Chemical speciation, Hazardous elements, Waste incineration plants, FLY-ASH, HEAVY-METALS, TRACE-ELEMENTS, COAL GANGUE, BEHAVIOR, COMBUSTION, MSW, RECOVERY, MERCURY, XPS


© 2022 Elsevier B.V.The transformation of heavy metals in ash from waste incineration plants is significant for ash management. The migration behavior of trace elements in ash after combustion, semidry deacidification, fabric filtration, and chelating agent stabilization was investigated from one waste incineration plant. The hazardous elements Zn, Pb, and As were enriched in raw fly ash (ash produced at a combustion temperature of 850–1100 °C) due to their relatively high volatility. Mercury, Cd, and Pb were captured in fly ash2 and processed by activated carbon and fabric filters. The removal rate of As (71%) was the highest among all studied elements due to a large amount of quinquevalent As removed. However, the average removal rate of elements in fly ash was only 13%. In the finally obtained fly ash3 (after chelating agent stabilization), a larger particle size (~100 μm) was found than that of raw ash. Furthermore, fly ash3 contains HgSO4 and trivalent As, which are toxic and likely to be precipitated when the fly ash3 is next utilized or deposited in a landfill, causing environmental risks.