SOLUTION PROPERTIES AND CHAIN STIFFNESS OF POLY(ACENAPHTHYLENE)

KUCUKYAVUZ, S; GOKSEL, C; KUCUKYAVUZ, Z

doi:10.1080/10601329308009435

SOLUTION PROPERTIES AND CHAIN STIFFNESS OF POLY(ACENAPHTHYLENE)

Atıf İçin Kopyala

KUCUKYAVUZ S., GOKSEL C., KUCUKYAVUZ Z.

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, sa.12, ss.907-917, 1993 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Basım Tarihi: 1993
Doi Numarası: 10.1080/10601329308009435
Dergi Adı: JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.907-917
Orta Doğu Teknik Üniversitesi Adresli: Hayır

Özet

Solution properties of poly(acenaphthylene) (PACN) were investigated in a theta solvent (1,2-dichloroethane) and a good solvent (chloroform). The viscosity exponent alpha was found to be 0.50 at both 35 and 41-degrees-C in 1,2-dichloroethane. Unperturbed dimensions found from viscometric measurements were compared with those of other vinyl aromatic polymers. Calculation of the chain flexibility parameters led to the conclusion that PACN is a rather stiff chain compared to other vinyl polymers with its characteristic ratio C(infinity) of 18.2 and chain flexibility parameter lambda of 7.